Title of article
Transition metal complexes in organic synthesis. Part 68: Iron-mediated total synthesis of mukonine and mukonidine by oxidative cyclization with air as the oxidizing agent
Author/Authors
Hans-Joachim Kn?lker، نويسنده , , Marcus Wolpert، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
6
From page
5317
To page
5322
Abstract
The oxidative cyclization of 5-(2-amino-5-methoxycarbonylphenyl)-substituted tricarbonyl[η4-cyclohexa-1,3-diene]iron complexes by air in protic medium provides the corresponding tricarbonyl[η4-4a,9a-dihydro-9H-carbazole]iron complexes. This procedure is applied to the total synthesis of the 3-methoxycarbonylcarbazole alkaloids mukonine and mukonidine.
Keywords
arylamines , carbazole alkaloids , electrophilic substitution , oxidative cyclization , Iron complexes
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1087957
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