Title of article
Synthesis of dimethylphosphorylamino diazo esters by a selective tandem Staudinger/Arbuzov rearrangement sequence of azido diazo esters with trimethylphosphite
Author/Authors
Marcus M. S?، نويسنده , , Gustavo P. Silveira، نويسنده , , Adailton J. Bortoluzzi، نويسنده , , Albert Padwa، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
7
From page
5441
To page
5447
Abstract
γ-Azido-α-diazo-β-keto esters react selectively with trimethylphosphite by a tandem Staudinger/Arbuzov rearrangement sequence, furnishing γ-(dimethylphosphorylamino)-α-diazo-β-keto esters in good yield under mild conditions. Collected X-ray data for the novel diazo phosphoramides confirm the proposed chemoselectivity.
Keywords
azido diazo esters , Staudinger reaction , diazo phosphoramide
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1087974
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