Title of article
Base-catalyzed condensation of cyclopentadiene derivatives. Synthesis of fulvalene analogues: strong proaromatic electron acceptors
Author/Authors
Emad Aqad، نويسنده , , Philippe Leriche، نويسنده , , Gilles Mabon، نويسنده , , Alain Gorgues، نويسنده , , Magali Allain، نويسنده , , Amédée Riou، نويسنده , , Arkady Ellern، نويسنده , , Vladimir Khodorkovsky، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
10
From page
5773
To page
5782
Abstract
A series of proaromatic electron acceptors derived from fulvenes were synthesized from tetrachlorocyclopentadiene and previously unknown 1,4-dicyano- and 1,4-dialkoxycarbonyl-2,3-dimethoxy cyclopentadienes. Two reversible one-electron reductions steps observed for fulvalenes coalesce into one two-electron reduction step upon increasing the length of the conjugating bridge.
Keywords
Condensation , fulvalene , Electron acceptors
Journal title
Tetrahedron
Serial Year
2003
Journal title
Tetrahedron
Record number
1088059
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