Title of article :
Effect of substituent on the enantioselectivity for lipase-catalyzed kinetic resolution of glycerol derivatives
Author/Authors :
Yasuhiro Kawanami، نويسنده , , Akira Honnma، نويسنده , , Kayo Ohta، نويسنده , , Naoko Matsumoto، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
The lipase-catalyzed transesterifications of various substituted diphenyl 1,2-ketals of glycerol have been investigated. Efficient modification of the substrate structure with bis(4-bromophenyl) ketal was found to enhance the enantioselectivity up to E=57 at 0 °C.
Keywords :
Substituent effect , Glycerol , Transesterification , Lipase , Kinetic resolution
Journal title :
Tetrahedron
Journal title :
Tetrahedron