Title of article
Chemoselective allylation of aldehydes using cerium(III) chloride: simple synthesis of homoallylic alcohols
Author/Authors
J.S. Yadav، نويسنده , , B.V.S. Reddy، نويسنده , , G. Kondaji، نويسنده , , J. Shyam Sunder Reddy، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
879
To page
882
Abstract
Aldehydes undergo smooth nucleophilic addition with allyltributylstannane in the presence of CeCl3·7H2O in acetonitrile under extremely mild reaction conditions to afford the corresponding homoallylic alcohols in excellent yields with high chemoselectivity. This method is very useful especially for the allylation of aldehydes bearing acid sensitive functionalities such as TBDMS, THP ethers, acetonides, aryl alkyl ethers and carbamates.
Keywords
homoallylic alcohols , Allyltin , Cerium reagents , Aldehydes
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1088315
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