Title of article
Concise total synthesis of (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-heneicosatriene, sex pheromone component of Hyphantria Cunea
Author/Authors
Xiao-Chao Che، نويسنده , , Zhong-ning Zhang and Ping Li ، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
7
From page
2187
To page
2193
Abstract
The total synthesis of (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-heneicosatriene, sex pheromone component of Hyphantria cunea, using a convergent synthetic strategy, was achieved through the regioselective coupling of the two fragments, chiral epoxy tosylate and 1,4-diyne. The former fragment was synthesized in two efficient and convenient approaches starting from the same available material using Sharpless AE kinetic resolution as the key step.
Keywords
Candia Rugosa lipase (CRL) , Enantioselectivity , Hydrolysis , ?-Hydroxy-?-arylpropionates , ?-Hydroxy-?-aryl-?-oxo-pentanoates
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1088447
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