Title of article
Barbier-type reaction mediated with tin nano-particles in water
Author/Authors
Zhenggen Zha، نويسنده , , Shu Qiao، نويسنده , , Jiaoyang Jiang، نويسنده , , Yusong Wang، نويسنده , , Qian Miao، نويسنده , , Zhiyong Wang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
7
From page
2521
To page
2527
Abstract
Tin nano-particles are employed in the Barbier-type allylation reaction of carbonyl compounds in water to afford the corresponding homoallylic alcohols in good yields. The in situ generated allylation intermediates, allyltin(II) bromide and diallyltin dibromide, have been directly observed by using 1H NMR. A mechanism is proposed based on this observation.
Keywords
Nano-particles , TIN , Barbier-type reaction , Water , mechanism
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1088480
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