Title of article
A new route to (±)-erythro-roccellic acid and chaetomellic anhydride C through functional rearrangement, promoted by n-propylamine or CH3ONa/CH3OH, of N-propyl-3-chloro-4-dichloromethyl-3-dodecylpyrrolidin-2-one
Author/Authors
Laurent De Buyck، نويسنده , , Chiara Danieli، نويسنده , , Franco Ghelfi، نويسنده , , Ugo M. Pagnoni، نويسنده , , Andrew F. Parsons، نويسنده , , Mariella Pattarozzi، نويسنده , , Fabrizio Roncaglia، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
7
From page
2871
To page
2877
Abstract
The rearrangement of a trichloro-pyrrolidin-2-one, prepared by the CuCl–TMEDA catalyzed atom transfer radical cyclization of N-alkyl-N-(3-chloro-2-propenyl)-2,2-dichloromyristamide, with n-propylamine or CH3ONa/CH3OH, is the key step of a new, short and inexpensive route to chaetomellic anhydride C and (±)-erythro-roccellic acid.
Keywords
Radicals , rearrangements , Cyclizations , pyrrolidinones
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1088515
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