Title of article
Superbase-promoted rearrangement of oxiranes to cyclopropanes
Author/Authors
Alessandro Mordini، نويسنده , , Daniela Peruzzi، نويسنده , , Francesco Russo، نويسنده , , Michela Valacchi، نويسنده , , Gianna Reginato، نويسنده , , Alberto Brandi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
12
From page
3349
To page
3360
Abstract
Aryl- and alkenyl substituted oxiranes, when submitted to treatment with superbasic reagents, undergo a highly regio- and stereoselective rearrangement leading to cyclopropylmethanol derivatives. The process can also be applied to mono- and dihydroxy substituted substrates thus leading to polyhydroxylated cyclopropanes.
Keywords
Cyclopropanes , rearrangement , 3-exo Cyclization , Superbase
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1088558
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