Author/Authors :
Mikl?s Nyerges، نويسنده , , David Bendell، نويسنده , , Andrea Arany، نويسنده , , David E. Hibbs، نويسنده , , Simon J. Coles، نويسنده , , Michael B. Hursthouse، نويسنده , , Paul W. Groundwater، نويسنده , , Otto Meth-Cohn، نويسنده ,
Abstract :
N-Metallated azomethine ylides were generated by the reaction of arylidene glycine imines with AgOAc and triethylamine. These azomethine ylides undergo cycloaddition to chiral acrylamides with excellent diastereoselectivity. The configuration of two of the cycloadducts was confirmed by X-ray crystallography.
Keywords :
azomethine ylide , Amines , Asymmetric , Cycloaddition , Pyrrolidine
