Title of article :
Intermolecular reductive coupling of hindered N-aryl imines towards the modular synthesis of chiral N-heterocyclic carbenes
Author/Authors :
Gregory J. Mercer، نويسنده , , Megan Sturdy، نويسنده , , David R. Jensen، نويسنده , , Matthew S. Sigman، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
We describe a simple method for the synthesis of hindered N-aryl diamines. The diastereoselectivity for these processes are relatively low but the diamines can be separated using either chromatography or selective crystallization. Separation of enantiomers can be accomplished using HPLC equipped with a chiral stationary phase.
Keywords :
N-Aryl , cross coupling , reductive coupling
Journal title :
Tetrahedron
Journal title :
Tetrahedron