Title of article :
Intermolecular reductive coupling of hindered N-aryl imines towards the modular synthesis of chiral N-heterocyclic carbenes
Author/Authors :
Gregory J. Mercer، نويسنده , , Megan Sturdy، نويسنده , , David R. Jensen، نويسنده , , Matthew S. Sigman، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Pages :
7
From page :
6418
To page :
6424
Abstract :
We describe a simple method for the synthesis of hindered N-aryl diamines. The diastereoselectivity for these processes are relatively low but the diamines can be separated using either chromatography or selective crystallization. Separation of enantiomers can be accomplished using HPLC equipped with a chiral stationary phase.
Keywords :
N-Aryl , cross coupling , reductive coupling
Journal title :
Tetrahedron
Serial Year :
2005
Journal title :
Tetrahedron
Record number :
1088856
Link To Document :
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