Title of article
Synthesis of polypropionate subunits from cyclopropanes
Author/Authors
Magali Defosseux، نويسنده , , Nicolas Blanchard، نويسنده , , Christophe Meyer، نويسنده , , Janine Cossy، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
22
From page
7632
To page
7653
Abstract
The oxymercuration–reductive demercuration of several cyclopropanealkanol or their derivatives bearing adjacent stereocenters has been investigated in order to synthesize polypropionate subunits. The crucial importance of the ester protecting group for the remote oxygenated moieties on the mechanism and the stereochemical outcome of these reactions has been rationalized.
Keywords
Electrophilic additions , Mercury , Diastereoselectivity , Cyclopropanes , Ring opening
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1088982
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