Title of article :
Michael additions catalyzed by phosphines. An overlooked synthetic method
Author/Authors :
Carolina Gimbert، نويسنده , , Maria Lumbierres، نويسنده , , Caroline Marchi، نويسنده , , Marcial Moreno-Ma?as، نويسنده , , Rosa M. Sebasti?n، نويسنده , , Adelina Vallribera، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2005
Abstract :
Triphenylphosphine and tributylphosphine are excellent catalysts for Michael additions. Many β-dicarbonyl compounds and electron-poor olefins, including sterically demanding partners, react successfully. The Michael addition catalyzed by phosphines deserves attention in its own right as a useful synthetic method.
Keywords :
Conjugate addition , ?-Dicarbonyl compounds , Organocatalysis , phosphines
Journal title :
Tetrahedron
Journal title :
Tetrahedron