Title of article
New enantioselective method for hydration of alkenes using cyclodextrins as phase transfer catalyst
Author/Authors
Artur R. Abreu، نويسنده , , Iva Costa، نويسنده , , Carla Rosa، نويسنده , , Lu?sa M. Ferreira، نويسنده , , Ana Lourenço، نويسنده , , Pedro P. Santos، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
5
From page
11986
To page
11990
Abstract
A new enantioselective/inverse phase transfer catalysis (IPTC) reaction for the Markovnikov hydration of double bounds by an oxymercuration–demercuration reaction with cyclodextrins as catalysts was disclosed. Moderate ee (up to 32%) and yields (14–60%) were obtained for allylic amines and protected allylic alcohols as starting materials.
Keywords
IPTC , Reduction , Cyclodextrin , Oxymercuration , Hydration
Journal title
Tetrahedron
Serial Year
2005
Journal title
Tetrahedron
Record number
1089414
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