Title of article
Exploring structural effects of levoglucosenone derived chiral auxiliaries in asymmetric Diels–Alder cycloadditions
Author/Authors
Ariel M. Sarotti، نويسنده , , Rolando A. Spanevello، نويسنده , , Carine Duhayon، نويسنده , , Jean-Pierre Tuchagues، نويسنده , , Alejandra G. Su?rez، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
11
From page
241
To page
251
Abstract
New chiral auxiliaries derived from levoglucosenone were developed in a simple and efficient way and evaluated as chiral inductors in asymmetric Diels–Alder reactions between the corresponding acrylate derivatives and cyclopentadiene. The results showed an important influence of the absolute configuration of the C(2) center of the auxiliary on the level of stereoinduction obtained.
Keywords
Cycloadditions , Acrylate , Chiral auxiliary , Levoglucosenone , Diels–Alder
Journal title
Tetrahedron
Serial Year
2007
Journal title
Tetrahedron
Record number
1090015
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