Title of article
Synthesis of galactosides locked in a 1,4B boat conformation and functionalized at the anomeric position
Author/Authors
Audrey Caravano، نويسنده , , Diane Baillieul، نويسنده , , Christophe Ansiaux، نويسنده , , Weidong Pan، نويسنده , , José Kovensky، نويسنده , , Pierre Sinay، نويسنده , , Stéphane P. Vincent، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
8
From page
2070
To page
2077
Abstract
A new methodology for the preparation of carbohydrates locked in a 1,4B boat conformation is presented. The constrained molecules thus obtained are functionalized at the anomeric position by iodo-, fluoro-, hydroxyl- or/and phosphono-methylene moieties. A remarkable diastereoselective opening of these quaternary acetals was also observed under non-acidic conditions.
Keywords
C-Glycosides , Boat conformation , ?-Fluoro-phosphonate , Glycals
Journal title
Tetrahedron
Serial Year
2007
Journal title
Tetrahedron
Record number
1090348
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