Author/Authors :
Takuya Kumamoto، نويسنده , , Yasuo Kitani، نويسنده , , Hideyoshi Tsuchiya، نويسنده , , Kentaro Yamaguchi، نويسنده , , Hiroko Seki، نويسنده , , Tsutomu Ishikawa، نويسنده ,
Abstract :
The first total synthesis of the proposed structure for methyl-kinamycin C (methyl-KC), derived from KC, was achieved via two key steps: Diels–Alder reaction of benzindenone and Danishefsky-type diene, and the stereoselective construction of highly oxygenated D ring. Good accordance of the spectral data of synthesized title compound with those of natural KC and its derivative was observed.
