Title of article
Microwave-assisted palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation
Author/Authors
Masayuki Iwasaki، نويسنده , , Sayuri Hayashi، نويسنده , , Koji Hirano، نويسنده , , Hideki Yorimitsu، نويسنده , , Koichiro Oshima، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
5200
To page
5203
Abstract
The palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation proceeds at 200–250 °C in a toluene–DMF mixed solvent using microwave heating. Even at such high temperatures, the regio- and stereospecificity of the allyl transfer reaction is still satisfactory. The amount of the palladium catalyst can be reduced to 0.5 or 0.05 mol %.
Keywords
Allylation , Palladium , Microwaves , Carbon–carbon bond cleavage
Journal title
Tetrahedron
Serial Year
2007
Journal title
Tetrahedron
Record number
1090925
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