Title of article
Palladium(II) mediated aziridination of olefins with bromamine-T as the nitrogen source: scope and mechanism
Author/Authors
Alexandra M.M. Antunes، نويسنده , , Vasco D.B. Bonif?cio، نويسنده , , Susana C.C. Nascimento، نويسنده , , Ana M. Lobo، نويسنده , , Paula S. Branco، نويسنده , , Sundaresan Prabhakar، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
9
From page
7009
To page
7017
Abstract
The palladium(II)-promoted reaction of a variety of olefins and bromamine-T provided N-tosyl-2-substituted aziridines under mild conditions. Olefins bearing chiral appendages gave only a poor to modest diastereoselectivity. Appropriate deuterated olefins were selected to study the stereochemistry of the reaction. A Pd(IV) intermediate is proposed as the aziridinating species.
Keywords
Bromamine-T , aziridination , Palladium(II) , Catalysis
Journal title
Tetrahedron
Serial Year
2007
Journal title
Tetrahedron
Record number
1091225
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