Author/Authors :
Marcello Tiecco، نويسنده , , Lorenzo Testaferri، نويسنده , , Claudio Santi، نويسنده , , Cristina Tomassini، نويسنده , , Stefano Santoro، نويسنده , , Francesca Marini، نويسنده , , Luana Bagnoli، نويسنده , , Andrea Temperini، نويسنده ,
Abstract :
Several unsaturated natural terpenes have been easily converted, in good yields, into the corresponding enantiomerically pure β-azidoselenides by addition of the electrophilic selenium reagent PhSeOTf in the presence of sodium azide. These reactions are stereospecific anti additions, which occur with a Markovnikov orientation. Examples of the synthetic importance of these β-azidoselenides are also reported.
