Author/Authors :
Takako Yamazaki، نويسنده , , Minoru Ishikawa، نويسنده , , Miki Uemura، نويسنده , , Yuko Kanda، نويسنده , , Hisashi Takei، نويسنده , , Morio Asaoka، نويسنده ,
Abstract :
The first enantioselective total synthesis of (+)-sarcodictyenone is described [4.3% overall yield from (5R,6R)-6-methyl-5-trimethylsily-2-cyclohexenone]. This work establishes the absolute stereochemistry of the natural product.
Keywords :
terpenoid , (+)-Sarcodictyenone , Hydroxycyclohexenone , Asymmetric synthesis