Author/Authors :
Akiharu Ueki، نويسنده , , Masafumi Hirota، نويسنده , , Yuta Kobayashi، نويسنده , , Keiko Komatsu، نويسنده , , Yutaka Takano، نويسنده , , Michio Iwaoka، نويسنده , , Yuko Nakahara، نويسنده , , Hironobu Hojo، نويسنده , , Yoshiaki Nakahara، نويسنده ,
Abstract :
β-Selective galactosylation was studied using a series of 2-O-benzylated phenyl 1-thio-galactosides and glycosyl acceptors in propionitrile with BSP–TTBP–Tf2O. The glycosylation enabled us to synthesize useful precursors of N-acetyllactosamine and core 1 O-glycoserine derivatives in a highly convergent manner.
Keywords :
Glycopeptide , Stereoselective synthesis of ?-galactoside , Propionitrile-assisted glycosylation , Thioglycoside
