Asymmetric total synthesis of the myxobacteria metabolites crocacins A–D
Author/Authors :
John T. Feutrill، نويسنده , , Michael J. Lilly، نويسنده , , Jonathan M. White، نويسنده , , Mark A. Rizzacasa، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Pages :
16
From page :
4880
To page :
4895
Abstract :
The total syntheses of crocacins A–D are described. The key steps were a syn-aldol reaction followed by anti-reduction to secure the stereotetrad and acylation of an ene- or dienecarbamate to form the enamide.