Title of article
α-Fluorination of β-ketosulfones by Selectfluor™ F–TEDA–BF4
Author/Authors
Hossein Loghmani-Khouzani، نويسنده , , Mohammad R. Poorheravi، نويسنده , , Majid M.M. Sadeghi، نويسنده , , Lorenzo Caggiano، نويسنده , , Richard F.W Jackson، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
7
From page
7419
To page
7425
Abstract
Attempted fluorination of β-ketosulfides using Selectfluor™ resulted only in the isolation of the corresponding diaryl disulfides, presumed to arise by decomposition of an unstable fluorinated intermediate. However, fluorination of β-ketosulfones using Selectfluor™ under anhydrous conditions does allow the isolation of both mono-and difluorinated products in moderate to good yields.
Keywords
Fluorination , Difluoromethylene , ?-Ketosulfones , Selectfluor™
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1094391
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