Title of article
Felkin–Anh selectivity in Rh(bisoxazolinylphenyl)-catalyzed reductive aldol coupling reaction: asymmetric synthesis of stereotriads
Author/Authors
Toru Hashimoto، نويسنده , , Junichi Ito، نويسنده , , Hisao Nishiyama، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
5
From page
9408
To page
9412
Abstract
The catalytic reductive aldol coupling of 2-phenylpropionaldehyde and acrylate derivatives with rhodium-bisoxazolinyl catalysts resulted in high Felkin–Anh selectivity (β,γ-syn) up to 98% accompanied by α,β-anti diastereoselectivity and high enantiomeric excesses up to 99%.
Keywords
Rhodium , Felkin–Anh , Bisoxazoline , Asymmetric catalysis , Reductive aldol reaction
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1094624
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