Title of article
Stereoselective synthesis of Certonardolsterol D3
Author/Authors
Biao Jiang، نويسنده , , He-ping Shi، نويسنده , , Min Xu، نويسنده , , Wanjun Wang، نويسنده , , Wei-Shan Zhou، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
7
From page
9738
To page
9744
Abstract
The first stereoselective synthesis of Certonardolsterol D3 was described. Ene reaction and improved allylic oxidation were employed as key steps for efficient construction of the desired 3β,6α,15β-triol steroidal framework. The chiral side chain in Certonardolsterol D3 was finally introduced by Julia olefination.
Keywords
ene reaction , Polyhydroxysterol , Julia olefination , Certonardolsterol
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1094667
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