Title of article :
Stereoselective synthesis of Certonardolsterol D3
Author/Authors :
Biao Jiang، نويسنده , , He-ping Shi، نويسنده , , Min Xu، نويسنده , , Wanjun Wang، نويسنده , , Wei-Shan Zhou، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
The first stereoselective synthesis of Certonardolsterol D3 was described. Ene reaction and improved allylic oxidation were employed as key steps for efficient construction of the desired 3β,6α,15β-triol steroidal framework. The chiral side chain in Certonardolsterol D3 was finally introduced by Julia olefination.
Keywords :
ene reaction , Polyhydroxysterol , Julia olefination , Certonardolsterol
Journal title :
Tetrahedron
Journal title :
Tetrahedron
