Title of article
Addition reactions of fluoroalkanesulfonyl azides to [60] fullerene under thermal or microwave irradiation condition
Author/Authors
Ran Wu، نويسنده , , Xiaoyong Lu، نويسنده , , Yun Zhang، نويسنده , , JIANMIN ZHANG، نويسنده , , Wanting Xiong، نويسنده , , Shizheng Zhu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
5
From page
10694
To page
10698
Abstract
The reactions of [60] fullerene with excess fluoroalkanesulfonyl azides RfSO2N3 in o-dichlorobenzene under thermal or microwave irradiation condition afforded monoadduct opened [5,6]-bridged azafulleroids. While, similarly treatment of 2,2,2-trifluoroethyl azides CF3CH2N3 with C60 gave two monoadducts, i.e., opened [5,6]-bridged azafulleroids, closed [6,6]-bridged Aziridino-fullerene, and some multi-addition product. A general mechanism for these addition reactions was proposed.
Keywords
Azafulleriod , Microwave irradiation , aziridino-fullerene , Fluoroalkylsulfonyl azides
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1094779
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