Title of article :
Chiral binuclear copper(II) catalyzed nitroaldol reaction: scope and mechanism
Author/Authors :
Suribabu Jammi، نويسنده , , Prasenjit Saha، نويسنده , , Sridhar Sanyashi، نويسنده , , Sekarpandi Sakthivel، نويسنده , , Tharmalingam Punniyamurthy، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2008
Abstract :
Chiral binuclear copper(II) Schiff base complexes 4a–g have been prepared from aldehydes 1a,b, (S)-amino alcohols 2a–f, and Cu(OAc)2·1H2O in high yield. Their catalysis is studied for the addition of nitroalkanes to aldehydes at ambient conditions with 76:24 er.
Keywords :
Bifunctional catalyst , Binuclear copper(II) complex , Homogeneous process , Nitroaldol reaction , Nitroalkanes , Aldehydes
Journal title :
Tetrahedron
Journal title :
Tetrahedron
