Title of article
Di-tert-butyl dicarbonate: a versatile carboxylating reagent
Author/Authors
John Kallikat Augustine، نويسنده , , Y. Arthoba Naik، نويسنده , , Veeramani Vairaperumal، نويسنده , , Sharmila Narasimhan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
5
From page
134
To page
138
Abstract
Carbon nucleophiles generated by a non-nucleophilic base (LDA) were effectively trapped with di-tert-butyl dicarbonate (Boc-anhydride) to provide the corresponding tert-butyl aryl acetates, di-tert-butyl aryl malonates, unsymmetrical aryl malonates and tert-butyl benzoates in high yields. This reaction represents another useful way to prepare a variety of tert-butyl carboxylates and highlights the synthetic utility of di-tert-butyl dicarbonate as a versatile carboxylating reagent.
Keywords
Non-nucleophilic base , Carboxylating reagent , Boc-anhydride , Carbon nucleophile , Di-tert-butyl malonate
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1094946
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