Author/Authors :
Zhijay Tu، نويسنده , , B. Rama Raju، نويسنده , , Tzuo-Rung Liou، نويسنده , , Veerababurao Kavala، نويسنده , , Chunwei Kuo، نويسنده , , Yaochung Jang، نويسنده , , Yu-Hsuan Shih، نويسنده , , Chun-Chao Wang، نويسنده , , Ching-Fa Yao، نويسنده ,
Abstract :
Friedel–Crafts alkylation of various arenes/heteroarenes to β-nitrostyrenes mediated by aluminum chloride is described. The interesting feature of this methodology pertain the formation of different products by tuning the reaction temperature. α-Arylated nitroalkanes were formed predominately at −78 °C, whereas α-arylated hydroximoyl chlorides were obtained at room temperature without any side products in high yields.
