Author/Authors :
Ian F. Cottrell، نويسنده , , Andrew R. Cowley، نويسنده , , Laura J. Croft، نويسنده , , Lauren Hymns، نويسنده , , Mark G. Moloney، نويسنده , , Ewan J. Nettleton، نويسنده , , H. Kirsty Smithies، نويسنده , , Amber L. Thompson، نويسنده ,
Abstract :
The reaction of lead(IV) tetracarboxylates with carboxylic acids containing unsaturated side chains has been found to give acyloxy lactone products in a diastereoselective process; the reaction can be extended to lead(IV) tetrazolates to give the analogous outcome. Mechanistic implications of these results are discussed.
Keywords :
Lead(IV) , Cyclisation , Carboxylic acids , Lactonisation
