Title of article
Unusual methylation reaction of gem-bromofluorospiropentanes with methyllithium
Author/Authors
Elena B. Averina، نويسنده , , Kseniya N. Sedenkova، نويسنده , , Ilya S. Borisov، نويسنده , , Yuri K. Grishin، نويسنده , , Tamara S. Kuznetsova، نويسنده , , Nikolai S. Zefirov، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
9
From page
5693
To page
5701
Abstract
A series of novel gem-bromofluorospiropentanes were synthesized and investigated in the reaction with methyllithium. Either substitution of the fluorine atom for a methyl group or rearrangement into methylated cyclobutene derivatives occurred under these conditions.
Keywords
Carbenoid rearrangement , gem-Dihalogenospiropentanes , Alkyllithium reagents , Fluorine substitution
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1097267
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