Title of article
Biocatalytic oxidation of benzyl alcohol to benzaldehyde via hydrogen transfer
Author/Authors
Thomas Orbegozo، نويسنده , , Iv?n Lavandera، نويسنده , , Walter M.F. Fabian، نويسنده , , Barbara Mautner، نويسنده , , Johannes G. de Vries، نويسنده , , Wolfgang Kroutil، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
5
From page
6805
To page
6809
Abstract
Various types of biocatalysts like oxidases, alcohol dehydrogenases, and microbial cells were tested for the oxidation of benzyl alcohol. Oxidases in combination with molecular oxygen led to low conversion. Alcohol dehydrogenases and microbial cells were tested in a hydrogen transfer reaction employing acetaldehyde, chloroacetone, and acetone as hydrogen acceptor. Excellent conversion (95%) could be achieved employing lyophilised cells of Janibacter terrae DSM 13953 at a substrate concentration of 97 mM.
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1097577
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