Title of article
Cycloaddition of annulated cyclohexa-2,4-dienones and novel reduction of halogen at bridgehead: an expedient route to tetracyclo[6.5.2.02,7.09,13]pentadec-2(7),11-dien-14-one and framework of conidiogenol and conidiogenone
Author/Authors
Vishwakarma Singh، نويسنده , , Raj Bahadur Singh، نويسنده , , Shaikh M. Mobin، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
6
From page
7969
To page
7974
Abstract
An expedient route to tetracyclo[6.5.2.02,7.09,13]pentadec-2(7),11-dien-14-one and tetracyclic framework of conidiogenol have been reported. Cycloaddition of annulated cyclohexa-2,4-dienone with cyclopentadiene, photochemical oxa-di-π-methane reaction and a highly unusual dehalogenation of bridgehead halogen are the key features of our methodology.
Keywords
Diels–Alder cycloaddition , Oxa-di-?-methane rearrangement , Spiroepoxycyclohexa-2 , 4-dienone , Photochemical reaction
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1097748
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