Author/Authors :
Mauricio Navarro Villalobos، نويسنده , , John L. Wood، نويسنده , , Susan Jeong، نويسنده , , Cristy Lindberg Benson، نويسنده , , Steven M. Zeman، نويسنده , , Catherine McCarty، نويسنده , , Matthew M. Weiss، نويسنده , , Analee Salcedo، نويسنده , , Jonathan Jenkins، نويسنده ,
Abstract :
The first total syntheses of (−)-syringolide 3, (+)-syributin 3 and their unnatural enantiomers (+)-syringolide 3 and (−)-syributin 3 using a common intermediate as starting material are described. In addition, total syntheses of (−)- and (+)-syributins 1 and 2 were accomplished by means of the same methodology.
Keywords :
Rhodium(II) stabilized carbene , O–H insertion , Syributins , Syringolides , Pseudomonas syringae , Total synthesis
