Title of article
Highly stereoselective epoxidation of O-protected 3-hydroxy-1-nitroalkenes
Author/Authors
Amit Jain، نويسنده , , Santiago Rodr?guez، نويسنده , , Irakusne L?pez، نويسنده , , Florenci V. Gonz?lez، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
5
From page
8362
To page
8366
Abstract
The diastereoselectivity of the nucleophilic epoxidation of O-protected 3-hydroxy-1-nitroalkenes was investigated. Epoxidation of the O-protected 3-hydroxy-1-nitroalkenes was highly stereoselective, giving rise to the anti isomer. The resulting nitroepoxides have been transformed into nitroaldols through hydrogenation. The nucleophilic epoxidation of nitroalkenes was found to be irreversible. Models to explain the observed stereoselectivities are proposed.
Keywords
nitrocompounds , Nitroaldols , Epoxidation
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1097795
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