Development of a palladium catalyzed addition of boronic acids to alkynyl esters: synthesis of trisubstituted olefins as single isomers
Author/Authors :
Alexander Graham Bush، نويسنده , , Jojo Liu Jiang، نويسنده , , Philippa R. Payne، نويسنده , , William W. Ogilvie، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Pages :
5
From page :
8502
To page :
8506
Abstract :
Very small phosphine ligands allow access to single isomer trisubstituted olefins from alkynyl esters with complete control of both stereochemistry and regiochemistry. This method provides a convenient synthesis of single isomer trisubstituted olefins without requiring olefin templates.
