Title of article
Reactivity of 1,2-cyclic sulfite xylosides towards nucleophiles
Author/Authors
Nathalie Batoux، نويسنده , , Christopher Hardacre، نويسنده , , Marie E. Migaud، نويسنده , , Kerry A. Ness، نويسنده , , Sarah E. Norman، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
5
From page
8858
To page
8862
Abstract
1,2-Cyclic sulfite xylosides offer facile access to 1,2-oxazolines upon reaction with aromatic and alkyl nitriles under Lewis or Brönsted acid conditions. Additionally, hydrophobic ionic liquids facilitate acid-catalysed formations of such oxazolines and C- and O-linked xylosides, providing means to carry out fast reactions at room temperature, and this in yields comparable to reactions conducted in xylene at high temperature for extended reaction time.
Keywords
Ionic liquids , Cyclic sulfites , C-Nucleosides , O-linked furanosides , C- , Oxazoline
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1097855
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