Title of article
Butyl lithium (nBuLi)-mediated carboxylation of vinylidenecyclopropanes with CO2
Author/Authors
Bei-Li Lu، نويسنده , , Jianmei Lu، نويسنده , , Min Shi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
8
From page
9328
To page
9335
Abstract
A novel butyl lithium (nBuLi)-mediated carboxylation of vinylidenecyclopropanes with CO2 in THF at −78 °C followed by the further transformation has been realized to afford the corresponding carboxylic adducts in moderate to good yields under normal conditions. The scope and limitations as well as the plausible reaction mechanism have been also discussed in this paper.
Keywords
Carboxylation , Vinylidenecyclopropane , Electrophile , nBuLi , Carbon dioxide , Carbolithiation adducts
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1099208
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