Title of article :
Organocatalyzed Tsuji–Trost reaction: a new method for the closure of five- and six-membered rings
Author/Authors :
Bojan Vulovic، نويسنده , , Filip Bihelovic، نويسنده , , Radomir Matovic، نويسنده , , Radomir N. Saicic، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2009
Abstract :
A combination of organotransition metal catalysis and organocatalysis allows for Tsuji–Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee.
Keywords :
enantioselective catalysis , cyclopentanes , cyclohexanes , Organocatalysis , ?-Allylpalladium complexes , Cyclization
Journal title :
Tetrahedron
Journal title :
Tetrahedron
