Title of article
Chemoselective reduction of azides catalyzed by molybdenum xanthate by using phenylsilane as the hydride source
Author/Authors
Mahagundappa R. Maddani، نويسنده , , Saravana K. Moorthy، نويسنده , , Kandikere R. Prabhu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
5
From page
329
To page
333
Abstract
A chemoselective, neutral, and efficient strategy for the reduction of azides to corresponding amines catalyzed by dioxobis(N,N,-diethyldithiocarbamato) molybdenum complex (1, MoO2[S2CNEt2]2) in the presence of phenylsilane is discovered. This chemoselective reduction strategy tolerates a variety of reducible functional groups.
Keywords
Molybdenum , Catalytic reduction , Silanes , Amines , Chemoselectivity
Journal title
Tetrahedron
Serial Year
2010
Journal title
Tetrahedron
Record number
1100433
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