Title of article
C–H⋯Br, C–Br⋯Br, and C–Br⋯π interactions in the crystal structures of mesitylene- and dimesitylmethane-derived compounds bearing bromomethyl units
Author/Authors
Monika Mazik، نويسنده , , Arno C. Buthe، نويسنده , , Peter G. Jones ، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
5
From page
385
To page
389
Abstract
X-ray structure determinations of mesitylene- and dimesitylmethane-derived compounds bearing bromomethyl units (compounds 1–3) show that the crystal packing of the molecules is characterized by the presence of C–H⋯Br interactions, such as BrCH2⋯Br, CH3⋯Br, and CPhH⋯Br. In addition, C–Br⋯Br and C–Br⋯π interactions determine the crystal packing. The bromomethyl groups play a major role in the packing of 1–3.
Keywords
Halogen bonds , Crystal engineering , Noncovalent interactions , Supramolecular chemistry , hydrogen bonds
Journal title
Tetrahedron
Serial Year
2010
Journal title
Tetrahedron
Record number
1100441
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