Title of article
Stereoselective intramolecular cyclization of γ-allylbenzamide via π–allylpalladium complex catalyzed by Pd(0)
Author/Authors
Van-Thoai Pham، نويسنده , , Jae-Eun Joo، نويسنده , , Kee-Young Lee، نويسنده , , Tai-Won Kim، نويسنده , , Yu Mu، نويسنده , , Won-Hun Ham، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
9
From page
2123
To page
2131
Abstract
An efficient procedure for synthesizing oxazines was developed by the palladium(0)-catalyzed intramolecular cyclization of a benzamide through a π-allylpalladium (II) complex. Interestingly, the diastereoselectivity of oxazine ring formation was dominantly controlled by the bulkiness of various protecting groups on the secondary alcohols.
Keywords
Chiral oxazine , Palladium catalysis , enantioselective catalysis , Intramolecular cyclization , Chiral building block
Journal title
Tetrahedron
Serial Year
2010
Journal title
Tetrahedron
Record number
1100642
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