Title of article :
Stereoselective intramolecular cyclization of γ-allylbenzamide via π–allylpalladium complex catalyzed by Pd(0)
Author/Authors :
Van-Thoai Pham، نويسنده , , Jae-Eun Joo، نويسنده , , Kee-Young Lee، نويسنده , , Tai-Won Kim، نويسنده , , Yu Mu، نويسنده , , Won-Hun Ham، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
An efficient procedure for synthesizing oxazines was developed by the palladium(0)-catalyzed intramolecular cyclization of a benzamide through a π-allylpalladium (II) complex. Interestingly, the diastereoselectivity of oxazine ring formation was dominantly controlled by the bulkiness of various protecting groups on the secondary alcohols.
Keywords :
Chiral oxazine , Palladium catalysis , enantioselective catalysis , Intramolecular cyclization , Chiral building block
Journal title :
Tetrahedron
Journal title :
Tetrahedron
