Title of article :
Applications of NHC-mediated O- to C-carboxyl transfer: synthesis of (±)-N-benzyl-coerulescine and (±)-horsfiline
Author/Authors :
Jennifer E. Thomson، نويسنده , , Andrew F. Kyle، نويسنده , , Kenneth B. Ling، نويسنده , , Siobhan R. Smith، نويسنده , , Alexandra M.Z Slawin، نويسنده , , Andrew D. Smith، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
NHC-promoted O- to C-carboxyl transfer of 3-allyl indolyl phenyl carbonates generates 3-allyl-3-phenoxycarbonyl-oxindoles with good catalytic efficiency, which are readily converted into (±)-N-benzyl-coerulescine and (±)-horsfiline.
Keywords :
Lewis-base catalysis , Organocatalysis , Carboxyl transfer , 3?-oxindole] , N-heterocyclic carbene
Journal title :
Tetrahedron
Journal title :
Tetrahedron
