Title of article :
Chemical reactivity of 6-diazo-5-oxo-l-norleucine (DON) catalyzed by metalloporphyrins (Fe,Ru)
Author/Authors :
Paul Le Maux، نويسنده , , Irène Nicolas، نويسنده , , Soizic Chevance، نويسنده , , Gérard Simonneaux، نويسنده ,
Issue Information :
هفته نامه با شماره پیاپی سال 2010
Abstract :
The transfer of the metallocarbene derived from N- and O-protected 6-diazo-5-oxo-l-norleucine (DON) catalyzed by metalloporphyrins undergoes dimerization, cyclopropanation, N–H and S–H insertion reactions, respectively. An efficient and direct synthesis of 5-oxo-l-pipecolic acid from DON is described from unprotected 6-diazo-5-oxo-l-norleucine.
Keywords :
Ruthenium porphyrin , Catalytic carbene transfer , Iron porphyrin , 6-Diazo-5-oxo-l-norleucine
Journal title :
Tetrahedron
Journal title :
Tetrahedron
