• Title of article

    An efficient synthesis of quinazolines: a theoretical and experimental study on the photochemistry of oxime derivatives

  • Author/Authors

    Rafael Alonso، نويسنده , , Alegr?a Caballero، نويسنده , , Pedro J. Campos، نويسنده , , Diego Sampedro، نويسنده , , Miguel A. Rodr?guez، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2010
  • Pages
    5
  • From page
    4469
  • To page
    4473
  • Abstract
    A new photochemical method for the preparation of quinazolines (2) through irradiation of [2-(methyleneamino)phenyl]methanone oximes (1) is reported. The photoreaction has been studied in depth by experimental, theoretical and photochemical methods. A six-electron electrocyclic ring closure mechanism, followed by water loss, is proposed and rationalized to explain the formation of quinazolines (2).
  • Keywords
    Theoretical calculations , Photochemistry , quinazolines , Oximes
  • Journal title
    Tetrahedron
  • Serial Year
    2010
  • Journal title
    Tetrahedron
  • Record number

    1100926