Author/Authors :
Marinella Roberti، نويسنده , , Benedetto Natalini، نويسنده , , Vincenza Andrisano، نويسنده , , Roberta Seraglia، نويسنده , , Antimo Gioiello، نويسنده , , Roberto Pellicciari، نويسنده ,
Abstract :
New stable [6,6]-methano cycloadducts and fulleropyrazolines containing electron-withdrawing groups have been obtained by the reaction of ethyl diazopyruvate with [60]fullerene. The results obtained by a systematic study conducted both in thermal and catalytic conditions have provided crucial indications concerning the mechanism of this important cluster opening process in fullerene chemistry.
Keywords :
Methanofullerene , Ethyl diazopiruvate , Fulleropyrazolines , Furanofullerene
