Title of article
Efficient synthesis of 19–31 membered macrocyclic tetralactones via ring closing metathesis in ionic liquids
Author/Authors
Sengodagounder Muthusamy، نويسنده , , Datschnamoorthy Azhagan، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
7
From page
8196
To page
8202
Abstract
The ring closing metathesis reaction in the presence of Grubbs catalyst was demonstrated using several ionic liquids to synthesize a range of macrocyclic tetralactones having ring size of 19 to 31 membered with different spacers. The ionic liquid [mmim][PF6] was found to be an excellent solvent and the recovery of the catalyst was demonstrated. X-ray analysis of a representative macrocyclic tetralactone was also reported.
Keywords
Grubbs catalyst , Ring closing metathesis , Ionic liquids , Macrocyclic tetralactones
Journal title
Tetrahedron
Serial Year
2010
Journal title
Tetrahedron
Record number
1101366
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