Title of article
Formation of unexpected products in the attempted aziridination of styrene with trifluoromethanesulfonyl nitrene
Author/Authors
Bagrat A. Shainyan، نويسنده , , Mikhail Yu. Moskalik، نويسنده , , Ines Starke، نويسنده , , Uwe Schilde، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
4
From page
8383
To page
8386
Abstract
The reaction of styrene with trifluoromethanesulfonyl nitrene generated from trifluoromethanesulfonamide in the system (t-BuOCl+NaI) results in the formation of trifluoro-N-[2-phenyl-2-(trifluoromethylsulfonyl)aminoethyl]methanesulfonamide, 1-phenyl-2-iodo-ethanol, and 2,5-diphenyl-1,4-bis(trifluoromethylsulfonyl)piperazine rather than the expected product of aziridination, 2-phenyl-1-(trifluoromethylsulfonyl)aziridine. The mechanism of the reaction is discussed.
Keywords
aziridination , Sulfonyl nitrenes , X-ray , DFT calculations , piperazines
Journal title
Tetrahedron
Serial Year
2010
Journal title
Tetrahedron
Record number
1101388
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