Title of article :
Palladium-Catalyzed Suzuki-Miyaura Reaction of Aryl Chlorides in Aqueous Media Using Tetrahydrodiazepinium Salts as Carbene Ligands
Author/Authors :
Ozdemir، Ismail نويسنده , , Gurbuz، Nevin نويسنده , , Gok، Yetkin نويسنده , , Cetinkaya، Engin نويسنده , , Ctinkaya، Bekir نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2005
Abstract :
A highly effective, easy to handle, and environmentally benign process for palladium-mediated Suzuki cross-coupling was developed. The in situ prepared three-component system of APd(OAc)2, 1,3-dialkyltetrahydrodiazepinium chlorides (2a-e), and K2CO3 catalyzes quantitatively the Suzuki-Miyaura cross-coupling of deactivated aryl chloride.
Keywords :
tetrahydrodiazepinium , Palladium , C-C coupling , N-heterocyclic carbene , Suzuki-Miyaura reaction
